Police are spraying protesters with water which quickly freezes their clothing, says Steve Rosenberg
Ukraine's President Viktor Yanukovych has offered the position of prime minister to an opposition leader, Arseniy Yatsenyuk.
The offer came after talks on Saturday with opposition leaders in a new effort to end the worsening unrest that has spread across the country.
Earlier, protesters in Kiev tried to occupy the energy ministry.
The protests began in November after Ukraine decided not to sign an accord on more co-operation with the EU.
Instead, the government opted to deepen ties with neighbouring Russia.
Offer of debates
The crisis escalated this week when two activists were killed, and another was found dead with torture marks in a forest near the capital.
A 45-year-old protester is said to have died in a Kiev hospital on Saturday, after sustaining injuries in earlier violence.
Arseniy Yatsenyuk (L) and Vitali Klitschko have been offered the positions of PM and deputy PM
The situation in Kiev remained tense on Saturday after further clashes between protesters and riot police
Mr Yatsenyuk, parliamentary leader of the country's second biggest party, Fatherland, has not commented on the president's offer.
He is an ally of the jailed ex-Prime Minister Yulia Tymoshenko.
Mr Yanukovych has also offered the post of deputy prime minister for humanitarian issues to the former boxer, Vitali Klitschko, who is leader of the Udar (Punch) movement.
Ukrainian media also report that Mr Yanukovych has said he is ready to amend the constitution to reduce the president's powers.
The opposition has previously demanded that Mr Yanukovych step down.
In a statement published on the government's website, Justice Minister Olena Lukash said that the president had offered public debates with Vitali Klitschko "in order to ensure a wide public dialogue," and that Mr Klitschko had agreed.
'Extremist' accusation
Earlier, Ukraine's interior minister said talks with protesters had failed.
Vitaliy Zakharchenko - in charge of the police and one of the figures most despised by the protesters - blamed "radical groups" for the unrest, adding that protesters had arms.
"We will consider those who remain on the Maidan [the square] and in captured buildings to be extremist groups," he said
"The events of recent days in the Ukrainian capital showed that our attempts to peacefully resolve the conflict without resorting to forceful opposition remain futile," he added.
Although the protest movement - the "EuroMaidan" - is largely peaceful, a hardcore of radicals have been fighting pitched battles with police away from the main protest on Independence Square.
Mr Zakharchenko accused the opposition of no longer able to control "radical forces" and of putting civilians in danger.
He also said that activists had shot a police officer and kidnapped three others - allegations denied as "false and dangerous" by protest leaders.
Later on Saturday, Mr Zakharchenko said protesters had released two officers, who were subsequently sent to hospital. Again, protesters called his words a provocation.
Orthodox priests have been urging security forces to refrain from using violence
The government has said peaceful negotiations had yielded no results, blaming the violence on "extremist" groups
The protests are taking place amid snowfall and freezing temperatures
On Friday protesters seized a number of government buildings in Ukrainian cities outside Kiev, particularly in the west, which has traditionally favoured closer ties with Europe, including in the cities of Chernivtsi, Ivano-Frankivsk, Lutsk and Lviv.
On Saturday the protests spread to cities further east, including Vinnytsya, just west of Kiev.
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